Unterschiede
Hier werden die Unterschiede zwischen zwei Versionen angezeigt.
| Nächste Überarbeitung | Vorhergehende Überarbeitung | ||
| en:materialdaten:dichtedaten_bzw._spezifisches_volumen [2024/04/11 15:21] – angelegt admin | en:materialdaten:dichtedaten_bzw._spezifisches_volumen [2025/05/15 15:06] (aktuell) – [Theoretical basics] cschall | ||
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| ======Density data or specific volume====== | ======Density data or specific volume====== | ||
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| + | ===== Material data - density ===== | ||
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| + | The following data of the material is entered in the ‘Density’ tab: | ||
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| + | * **Solids density**: The density of the compact solid | ||
| + | * **Bulk density**: The bulk density of the granulate or flakes. Is inevitably lower than the solid density | ||
| + | * **Calculation method**: Optionally density function (with 3 parameters) or volume function (with 2 parameters). See below for details. | ||
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| + | {{ : | ||
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| + | ===== Theoretical basics ===== | ||
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| + | Both the density and the specific volume as well as the glass transition or crystalline | ||
| + | melting point can be determined from the pvT-diagram. | ||
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| + | {{ : | ||
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| + | The crystallite melting temperature $T_K$ is defined by the inflection point of the specific volume function in the pvT diagram. The glass transition temperature $T_G$ can be determined as the intersection of the tangents at the upper and lower course of the volume function. | ||
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| + | ==== Density function ==== | ||
| + | |||
| + | The density function requires the three input values | ||
| + | * **Specific density** $\rho_0$: Corresponds to the density extrapolated to 0 °C (by default for a pressure of 100 bar) | ||
| + | * **Slope of the density function** $\rho_m$: Corresponds (for positive value) to the **decrease** in density per 1 °C | ||
| + | * **Compressibility value** $\kappa$: Describes the pressure dependence of the density | ||
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| + | The temperature-dependent density of the melt can be described by the following linear equation | ||
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| + | \[ρ = ρ_0 - ρ_m \cdot T\] | ||
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| + | If only one density value is available, make sure that this value corresponds to the mass temperature in the process and that the gradient $\rho_m$ is zero. Otherwise, the value $ρ_0$ at $0 °C$ should be entered with the corresponding temperature dependence $\rho_m$. | ||
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| + | The compressibility $\kappa$ (order of magnitude 0.0001 1/bar, reciprocal of the bulk modulus K) influences the density as a function of the pressure: | ||
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| + | $$ \kappa = \frac{1}{K} = - \frac{1}{V} \frac{dV}{dp} $$ | ||
| + | $$\text{with}$$ | ||
| + | $$\frac{dV}{V} = - \frac{d \rho}{\rho}$$ | ||
| + | $$\text{is}$$ | ||
| + | $$\frac{\Delta \rho}{\rho} = \kappa \cdot \Delta p$$ | ||
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| + | The value kappa can be imported directly from PAM or entered manually. If the value 0 is set for kappa, the density is calculated without taking the pressure into account. | ||
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| + | ==== Volume function ==== | ||
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| + | The function of the specific volume as the reciprocal of the density contains only two parameters: | ||
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| + | \[v = v_0 + v_m \cdot T\] | ||
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| + | The two characteristic values $v_0$ and $v_m$ can also be determined from the pvT diagram, whereby the data must be determined at an average pressure corresponding to the process. \\ | ||
| + | The modelling of the specific volume cannot take pressure dependency into account. | ||
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| + | ===Further topics=== | ||
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